Effect of the tether length upon Truce-Smiles rearrangement reactions
نویسندگان
چکیده
منابع مشابه
Metal Free Bi(hetero)aryl Synthesis: A Benzyne Truce–Smiles Rearrangement
A new benzyne transformation is described that affords versatile biaryl structures without recourse to transition-metal catalysis or stoichiometric amounts of organometallic building blocks. Aryl sulfonamides add to benzyne upon fluoride activation, and then undergo an aryl Truce-Smiles rearrangement to afford biaryls with sulfur dioxide extrusion. The reaction proceeds under simple reaction co...
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ژورنال
عنوان ژورنال: Journal of Physical Organic Chemistry
سال: 2017
ISSN: 0894-3230
DOI: 10.1002/poc.3742